26155
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26155
Fluka
(S)-(−)-2-Chloropropionic acid
puriss., ≥98.5% (sum of enantiomers, GC)
| Synonym: | (S)-(−)-2-Chloropropanoic acid, |
| CAS Number: | 29617-66-1 |
| Linear Formula: | C3H5ClO2 |
| Molecular Weight: | 108.52 |
| Beilstein Registry Number: | 1720257 |
| EC Number: | 411-150-5 |
| MDL number: | MFCD00064205 |
Description
| Other Notes | Chiral building block; it is used in the synthesis of muramic acid derivatives 1,2; Preparation of its tert-butyl ester and reaction with protected amino acid cesium salts to depsipeptides 3 |
Properties
| grade | puriss. |
| assay | ≥98.5% (sum of enantiomers, GC) |
| optical activity | [α]20/D −14±0.5°, neat |
| refractive index | n |
| bp | 185-188 °C |
| density | 1.258 g/mL at 20 °C(lit.) |
Safety
| Personal Protective Equipment | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes | C |
| Risk Statements | 21/22-35 |
| Safety Statements | 23-26-28-36/37/39-45 |
| RIDADR | UN2511 8/PG 3 |
| WGK Germany | 1 |
| RTECS | UA2451950 |
| Flash Point(F) | 140 °F |
| Flash Point(C) | 60 °C |
Related Products
| Replaced by | 306797, (S)-(−)-2-Chloropropionic acid |
References
| Cited Reference | 1. S. Kusumoto et al. Bull. Chem. Soc. Jpn. 59, 1411, (1986) |
| 2. H. Paulsen et al. Liebigs Ann. Chem., 664, (1986) | |
| 3. H.G. Lerchen, H. Kunz Tetrahedron Lett. 26, 5257, (1985) | |
| Beilstein | Beil. 2,IV,745 |
